Validation of Models Predicting Nucleation Rates from Induction Times and Metastable Zone Widths

Three approaches for estimation of nucleation rates from induction time and metastable zone width (MSZW) were validated based on directly measured nucleation rates for paracetamol in ethanol. To quantitatively predict nucleation kinetics using Kubota's methods it is necessary to know the minimum detectable number concentration of nuclei. This was found by determination of light transmission of a series of diluted suspensions of newly nucleated crystals where the size had already been assessed by optical reflection measurement (ORM). The measured nucleation rates strongly depended on both temperature and supersaturation. The Nyvlt method predicted nucleation rates in this system reasonably well; however, it gave slightly low estimates for all temperatures. The methods of Kubota provided nucleation rates that were low by an order of magnitude.     

Real‐time monitoring by proton relaxometry of radical polymerization reactions of acrylamide in aqueous solution

The potential of time‐domain nuclear magnetic resonance (TD‐NMR) for the real‐time monitoring of solution radical polymerizations is demonstrated. A model system composed of a redox‐pair initiator system, acrylamide as monomer and water as solvent was investigated. A second‐generation continuous wave free precession technique was employed to measure the longitudinal relaxation time constant (T₁) of the samples throughout the polymerization reactions. This parameter was shown to be sensitive to the reactant feed free‐radical enhancement of the water molecule relaxation time, making it a good probe to monitor monomer conversion in real time in an automated, non‐destructive fashion. It was found that the T₁ value was better than the transverse relaxation time constant (T₂) for describing the evolution of the polymerization reactions, due to its greater sensitivity to paramagnetic effects. The TD‐NMR signal variation observed was linked to the formation, propagation and termination steps of the radical polymerization kinetics scheme. These first results may contribute to the application of real‐time monitoring of radical polymerization reactions employing low‐cost and robust TD‐NMR spectrometers. © 2018 Society of Chemical Industry     

大螺距连续螺旋折流板换热器制造工艺研究

针对大螺距连续螺旋折流板螺旋升角大、成型困难的问题，分析了连续螺旋板成型的基本原理，提出了螺旋导向+热成型+周向力的成型方案，设计制造了连续螺旋折流板压制成型模具，压制过程中通过模具转动得到了一个完整周期的连续螺旋折流板；分析了大螺距连续螺旋折流板钻孔加工的难点，提出了采用数控加工中心铣削加工的方案。通过合理的刀具选择和装夹设计加工出了连续螺旋折流板，解决了大螺距螺旋面管孔加工问题，为大螺距连续螺旋折流板的成型及加工提供了借鉴。     

Functional Causality between Oil Prices and GDP Based on Big Data

This paper examines the causal relationship between oil prices and the Gross Domestic Product (GDP) in the Kingdom of Saudi Arabia. The study is carried out by a data set collected quarterly, by Saudi Arabian Monetary Authority, over a period from 1974 to 2016. We seek how a change in real crude oil price affects the GDP of KSA. Based on a new technique, we treat this data in its continuous path. Precisely, we analyze the causality between these two variables, i.e., oil prices and GDP, by using their yearly curves observed in the four quarters of each year. We discuss the causality in the sense of Granger, which requires the stationarity of the data. Thus, in the first Step, we test the stationarity by using the Monte Carlo test of a functional time series stationarity. Our main goal is treated in the second step, where we use the functional causality idea to model the co-variability between these variables. We show that the two series are not integrated; there is one causality between these two variables. All the statistical analyzes were performed using R software.     

基于LSTM-RF模型的城市道路交通流预测

交通流预测作为信号协调和出行时间预测等任务的基础,成为了交通领域的研究点。对于交通流预测问题,研究人员提出了多种方法,但这些方法大多只使用交通流数据的时域信息进行交通流预测,忽略了空间相关性对于预测目标路段流的影响,导致预测精度不理想。基于组合模型的思想提出了一种称为LSTM-RF的交通流预测模型。在交通流预测过程中,首先使用LSTM模型提取预测目标路段的时序特征,再将其预测值与采集的相邻上下游路段信息同时作为随机森林模型的输入特征,进行交通流时空相关性分析,获得最终的预测结果。并通过贵阳市车牌识别系统采集的城区132条路段的交通流数据进行实验验证。结果表明:该方法在预测精度上优于单一模型,并且预测误差相比单一模型有明显减少。     

Nb和时效时间对热轧中锰TRIP钢中P偏聚的影响

热轧态中锰TRIP钢首先经650 ℃退火2 h,随后在550 ℃进行等温时效热处理,采用场发射扫描电镜(FE-SEM)研究该钢中P的偏聚和时效析出行为的变化情况。结果表明,中锰TRIP钢中P在晶界的偏聚是一种非平衡偏聚现象,临界时间约为50 h,与理论计算结果48 h较为吻合。在局部偏聚区域内,C与P存在共偏聚的关系,即P偏聚量高的地方,C含量也高。而合金元素Nb具有抑制P偏聚的效果,在20~70 h时效时间内,可以相对降低6.57%~19.5%的最大P偏聚量。根据电子背散射衍射(EBSD)菊池线分析,P偏聚量低于2.28at%时,P为固溶状态,高于2.28at.%时,P为析出状态。     

变厚度板中水平剪切波的传播特性分析

为研究超声导波在储罐壁板等变壁厚结构中的传播特性，建立了SH波在空间自由边界中的传播模型，基于各向同性弹性介质Navier-Stokes方程，推导了变厚度板中SH波的频散方程，分析了变厚度板中水平剪切波走时t与倾斜角θ间的相互作用关系；通过简谐点源的远场响应并引入板厚与传播位移的非线性关系，得出了变厚度板中SH波的远场响应方程。在此基础上，仿真分析和实验验证了水平剪切波在不同倾斜角变厚度板中的传播特性，结果表明：在变厚度板的薄端激励水平剪切波并沿结构表面传播时，无频散现象，且无波包分离现象；但随着变厚度板倾斜角θ增大，水平剪切波的走时和接收信号幅值均逐渐递减，且呈非线性关系。     

超深溜井爆破一次成井技术实践

为解决溜井掘进效率低、安全性差等问题，以柿竹园多金属矿掘进出矿溜井为例，提出了爆破一次成井技术，根据矿山具体爆破条件，设计了布孔参数、装药结构和起爆顺序等。实践表明，爆破一次成井技术施工天井效果良好，溜井贯穿上下2个分段，与设计相符，相较于普通法施工天井，节约成本30.7%，节约时间58.3%，经济效益显著，施工周期短，且安全性好，值得在其他类似矿山推广应用。     

Use of conditioning time to investigate the mechanisms of interactions of selected fatty acids on hematite Part II laboratory investigations

It is the aim of this paper to examine the effects of conditioning time on the flotation of hematite using three technical grade fatty acid reagents as providing additional evidence on their mechanism of interaction with the hematite surface. Various mechanisms have been postulated as occurring as conditioning time is increased. Both physical (e.g. conditioning time and power input) and chemical (nature, dispersion and solubility of the adsorbing species) contribute to the mechanisms of attachment of collector. In this paper, the mechanism of attachment of oleate to hematite can be readily explained by chemisorption, but the mechanism of attachment of lauric acid appears to be physical adsorption at neutral pH. The flotation of hematite with a mixture of tallow-type fatty acids (palmitic, stearic and oleic acids) is very sensitive to conditioning time, and suggests that, even though flotation is very effective at short conditioning times, it is very susceptible to the presence of fines and their associated high surface areas. It is therefore obvious that both the physical and chemical conditions contribute to the mechanisms of adsorption of fatty acids on iron-containing oxide minerals and must be understood in order to optimise the flotation of these minerals in an industrial situation.     

Profit maximization of TSP through a hybrid algorithm

Here a new model of Traveling Salesman Problem (TSP) with uncertain parameters is formulated and solved using a hybrid algorithm. For this TSP, there are some fixed number of cities and the costs and time durations for traveling from one city to another are known. Here a Traveling Salesman (TS) visits and spends some time in each city for selling the company’s product. The return and expenditure at each city are dependent on the time spent by the TS at that city and these are given in functional forms of t. The total time limit for the entire tour is fixed and known. Now, the problem for the TS is to identify a tour program and also to determine the stay time at each city so that total profit out of the system is maximum. Here the model is solved by a hybrid method combining the Particle Swarm Optimization (PSO) and Ant Colony Optimization (ACO). The problem is divided into two subproblems where ACO and PSO are used successively iteratively in a generation using one’s result for the other. Numerical experiments are performed to illustrate the models. Some behavioral studies of the models and convergences of the proposed hybrid algorithm with respect to iteration numbers and cost matrix sizes are presented.